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Publication --> 2012

"Studies on Catalytic Enantioselective Total Synthesis of Caprazamycin B: Construction of the Western Zone"
Gopinath, P.; Watanabe, T.; Shibasaki, M.
J. Org. Chem. 2012, 77, 9260.


"Synthesis and Assignment of the Absolute Configuration of Indenotryptoline Bisindole Alkaloid BE-54017"
Kimura, T.; Kanagaki, S.; Matsui, Y.; Imoto, M.; Watanabe, T.; Shibasaki, M.
Org. Lett. 2012, 14, 4418.


"Direct asymmetric ƒ¿-allylation of ketones with allylic alcohols via Pd/enamine cooperative function"
Yasuda, S.; Kumagai, N.; Shibasaki, M.
Heterocycles 2012, 86, 745.


"Catalytic Asymmetric Conjugate Addition of Thiols to ƒ¿,ƒÀ-Unsaturated Thioamides: Expeditious Access to Enantioenriched 1,5-Benzothiazepines"
Ogawa, T.; Kumagai, N.; Shibasaki, M.
Angew. Chem. Int. Ed. 2012, 51, 8551.


"Catalytic Asymmetric Synthesis of Spirooxindoles by a Mannich-Type Reaction of Isothiocyanato Oxindoles"
Kato, S.; Yoshino, T.; Shibasaki, M.; Kanai, M.; Matsunaga, S.
Angew. Chem. Int. Ed. 2012, 51, 7007.


"Anti-Selective Direct Catalytic Asymmetric Aldol Reaction of Thiolactams"
Sureshkumar, D.; Kawato, Y.; Iwata, M.; Kumagai, N.; Shibasaki, M.
Org. Lett. 2012, 14, 3018.


"Concise Enantioselective Synthesis of Duloxetine via Direct Catalytic Asymmetric Aldol Reaction of Thioamide"
Suzuki, Y.; Iwata, M.; Yazaki, R.; Kumagai, N.; Shibasaki, M.
J. Org. Chem. 2012, 77, 4496.


"Catalytic Asymmetric Total Synthesis of Chimonanthine, Folicanthine, and Calycanthine through Double Michael Reaction of Bisoxindole"
Mitsunuma, H.; Shibasaki, M.; Kanai, M.; Matsunaga, S.
Angew. Chem. Int. Ed. 2012, 51, 5217.


"A Direct Catalytic Asymmetric Aldol Reaction of ƒ¿-Sulfanyl Lactones: Efficient Synthesis of SPT Inhibitors"
Takechi, S.; Yasuda, S.; Kumagai, N.; Shibasaki, M.
Angew. Chem. Int. Ed. 2012, 51, 4218.


"Asymmetric Synthesis of Dihydropyranones from Ynones by Sequential Copper(I)-Catalyzed Direct Aldol and Silver(I)-Catalyzed Oxy-Michael Reactions"
Shi, S.-L.; Kanai, M.; Shibasaki, M.
Angew. Chem. Int. Ed. 2012, 51, 3932.


"Catalytic Enantioselective Desymmetrization of meso-Glutaric Anhydrides Using a Stable Ni2-Schiff Base Catalyst"
Gopinath, P.; Watanabe, T.; Shibasaki, M.
Org. Lett. 2012, 14, 1358.


"Reversible Heterochiral Aggregation/Dissociation of Bis(2-hydroxyphenyl)diamides Driven by UV/Vis Irradiation"
Nojiri, A.; Kumagai, N.; Shibasaki, M.
Angew. Chem. Int. Ed. 2012, 51, 2137.


"Catalytic Asymmetric anti-Selective Nitroaldol Reaction En Route to Zanamivir"
Nitabaru, T.; Kumagai, N.; Shibasaki, M.
Angew. Chem. Int. Ed. 2012, 51, 1644. (selected as a hot paper)


"Intermediate as Catalyst: Catalytic Asymmetric Conjugate Addition of Nitroalkanes to ƒ¿,ƒÀ-Unsaturated Thioamides"
Ogawa, T.; Mouri, S.; Yazaki, R.; Kumagai, N.; Shibasaki, M.
Org. Lett. 2012, 14, 110.