Bimetallic Schiff Base

> Mannich-type Reaction
> syn-Selective Nitro-Mannich-type Reaction
> anti-Selective Nitroaldol Reaction

Review:
Synlett 2008, 1583.
Mannich-type Reaction



Chen, Z.; Morimoto, H.; Matsunaga, S.; Shibasaki, M. J. Am. Chem. Soc. 2008, 130, 2170.
Chen, Z.; Yakura, K.;Matsunaga, S.; Shibasaki. M. Org. Lett. 2008, 10, 3239.
syn-Selective Nitro-Mannich-type Reaction



Handa, S.; Gnanadesikan, V.; Matsunaga, S.; Shibasaki, M. J. Am. Chem. Soc. 2007, 129, 4900.
anti-Selective Nitroaldol Reaction



Handa, S; Nagawa, K; Sohtome, Y; Matsunaga, S; Shibasaki, M. Angew. Chem. Int. Ed. 2008, 47(17), 3230.
Sohtome, Y; Kato, Y; Handa, S; Aoyama, N; Nagawa, K; Matsunaga, S; Shibasaki, M. Org. Lett. 2008, 10, 2231.
(Editor: Y. Xu, K. Nagawa)

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