Copper(I)-Fluoride System

> Catalytic Asymmetric Allylation
> Catalytic Asymmetric Aldol Reaction
> Direct Catalytic Asymmetric Cyanomethylation
> Catalytic Asymmetric Alkenyllation and Phenylation
> Catalytic Asymmetric Reductive Aldol Reaction
Catalytic Asymmetric Allylation of Ketones / Ketoimines



Yamasaki, S.; Fujii, K.; Wada, R; Kanai. M.; Shibasaki, M. J. Am. Chem. Soc. 2002, 124, 6536-6537.



Wada, R.; Oisaki, K.; Kanai, M.; Shibasaki, M. J. Am. Chem. Soc. 2004, 126, 8910-8911.


Wada, R.; Shibuguchi, T.; Makino, S.; Oisaki, K.; Kanai, M.; Shibasaki, M. J. Am. Chem. Soc. 2006, 128, 7687-7691.
Catalytic Asymmetric Aldol Reaction of Ketones



Oisaki, K.; Suto, Y.; Kanai, M.; Shibasaki. M. J. Am. Chem. Soc. 2003, 125, 5644 - 5645.



Oisaki,K.; Zhao,D.; Suto, Y.; Kanai, M.; Shibasaki, M. Tetrahedron Lett. 2005, 46, 4325.
Oisaki,K.; Zhao,D.; Kanai, M.; Shibasaki, M. J. Am. Chem. Soc. 2006, 128, 7164-7165.
Direct Catalytic Asymmetric Cyanomethylation



Suto, Y.; Kumagai, N.; Matsunaga, S.; Kanai, M.; Shibasaki, M. Org. Lett. 2003, 5, 3147-3150.

Suto, Y.; Tsuji, R.; Kanai, M.; Shibasaki, M. Org. Lett. 2005, 7, 3757-3760.
Catalytic Asymmetric Alkenylation and Phenylation



Tomita, D.; Wada, R.; Kanai, M.; Shibasaki, M. J. Am. Chem. Soc. 2005, 127, 4138-4139.
Catalytic Asymmetric Reductive Aldol Reaction to Ketones


Zhao, D.; Oisaki, K.; Kanai, M.; Shibasaki, M. Tetrahedron Lett. 2006, 47, 1403.

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